|
|
Dihydrosanguinarine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 10-Hydroxydihydrosanguinarine + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.100
dihydrosanguinarine 10-monooxygenase
|
–
|
| |
MetaCyc:
1.14.13.56-RXN
|
|
|
|
(S)-scoulerine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> (S)-cheilanthifoline + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.19.65
(S)-cheilanthifoline synthase
|
–
|
| |
MetaCyc:
1.14.21.2-RXN
|
|
|
|
H+ + O2 + Dihydrosanguinarine <=> H2O2 + sanguinarine
|
1.3.3.8
tetrahydroberberine oxidase
1.5.3.12
dihydrobenzophenanthridine oxidase
|
–
–
|
| |
BRENDA:
BR1308
KEGG:
R04703
MetaCyc:
1.5.3.12-RXN
|
|
|
|
(S)-scoulerine + reduced_[NADPH-hemoprotein_reductase] + O2 <=> (S)-nandinine + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.19.73
(S)-nandinine synthase
|
–
|
| |
MetaCyc:
RXN-15538
|
|
|
|
S-adenosyl-L-methionine + 12-hydroxydihydrochelirubine <=> H+ + S-adenosyl-L-homocysteine + Dihydromacarpine
|
2.1.1.120
12-hydroxydihydrochelirubine 12-O-methyltransferase
|
–
|
| |
BRENDA:
BR1442
KEGG:
R04705
MetaCyc:
2.1.1.120-RXN
|
|
|
|
Dihydrosanguinarine + NADP+ <=> sanguinarine + NADPH
|
1.3.1.107
sanguinarine reductase
|
–
|
| |
BRENDA:
BR51080
KEGG:
R10799
MetaCyc:
RXN-9276
|
|
|
|
O2 + (S)-reticuline <=> H+ + H2O2 + (S)-scoulerine
|
1.21.3.3
reticuline oxidase
|
–
|
| |
BRENDA:
BR36965
KEGG:
R03831
MetaCyc:
RETICULINE-OXIDASE-RXN
|
|
|
|
H+ + Dihydromacarpine + O2 <=> Macarpine + H2O2
|
1.5.3.12
dihydrobenzophenanthridine oxidase
|
–
|
| |
BRENDA:
BR48017
KEGG:
R04768
MetaCyc:
RXN-8183
|
|
|
|
protopine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 6-hydroxyprotopine + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.98
protopine 6-monooxygenase
|
–
|
| |
MetaCyc:
1.14.13.55-RXN
|
|
|
|
S-adenosyl-L-methionine + 10-Hydroxydihydrosanguinarine <=> H+ + S-adenosyl-L-homocysteine + dihydrochelirubine
|
2.1.1.119
10-hydroxydihydrosanguinarine 10-O-methyltransferase
|
–
|
| |
BRENDA:
BR1440
KEGG:
R04707
MetaCyc:
2.1.1.119-RXN
|
|
|
|
(S)-cis-N-Methylstylopine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> protopine + H2O + oxidized_[NADPH-hemoprotein_reductase] + H+
|
1.14.14
|
–
|
| |
MetaCyc:
RXN-8180
|
|
|
|
H+ + dihydrochelirubine + O2 <=> chelirubine + H2O2
|
1.5.3.12
dihydrobenzophenanthridine oxidase
|
–
|
| |
BRENDA:
BR48016
KEGG:
R04706
MetaCyc:
RXN-9275
|
|
|
|
S-adenosyl-L-methionine + (S)-Stylopine <=> (S)-cis-N-Methylstylopine + S-adenosyl-L-homocysteine
|
2.1.1
2.1.1.122
(S)-tetrahydroprotoberberine N-methyltransferase
|
–
–
|
| |
KEGG:
R04691
MetaCyc:
RXN-8179
|
|
|
|
dihydrochelirubine + NADP+ <=> chelirubine + NADPH
|
1.3.1.107
sanguinarine reductase
|
–
|
| |
BRENDA:
BR51081
KEGG:
R10801
MetaCyc:
RXN-15514
|
|
|
|
(S)-cheilanthifoline + O2 + reduced_[NADPH-hemoprotein_reductase] <=> (S)-Stylopine + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.19.64
(S)-stylopine synthase
|
–
|
| |
MetaCyc:
1.1.3.32-RXN
|
|
|
|
6-hydroxyprotopine <=> Dihydrosanguinarine + H2O
|
not assigned
|
–
|
| |
KEGG:
R04701
MetaCyc:
RXN-8181
|
|
|
|
dihydrochelirubine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 12-hydroxydihydrochelirubine + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.101
dihydrochelirubine 12-monooxygenase
|
–
|
| |
MetaCyc:
1.14.13.57-RXN
|
|
